(Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)hydroxidocopper(II) monohydrate
نویسندگان
چکیده
In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4'-dimethyl-2,2'-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid mol-ecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a 'free' benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water mol-ecule is equally disordered over two positions. The structure displays O-H⋯O hydrogen bonding.
منابع مشابه
(4,4′-Dimethyl-2,2′-bipyridine-κ2 N,N′)(dimethylformamide-κO)diiodidocadmium
In the title compound, [CdI2(C12H12N2)(C3H7NO)], the Cd(II) cation is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide ligand and two I(-) anions. π-π stacking between pyridine rings of adjacent mol-ecules [centroid-centroid distance = 3.666 (3) and 3.709 (4) Å] stabilizes the thre...
متن کاملDibenzoato-κO;κ2 O,O′-(6,6′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc(II)–benzoic acid (1/1)
In the crystal structure of the title compound, [Zn(C(6)H(5)COO)(2)(C(12)H(12)N(2))]·C(6)H(5)COOH, the Zn atom is penta-coordinated in distorted square-pyramidal geometry by two O atoms of a benzoate anion and two N atoms of a 6,6'-dimethyl-2,2'-bipyridine ligand occupying the basal plane and an O atom of another benzoate anion located at the apical site. In the crystal structure, inter-molecul...
متن کامل(4,4′-Dimethyl-2,2′-bipyridine-κ2 N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl sulfoxide mol-ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra-molecular C-H⋯O hydrogen bonds and inter-molecular π-π stacking inter-actions between the pyridine rings [centroid-centroid distanc...
متن کاملAqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)(nitrato-κO)(nitrato-κ2 O,O′)zinc
In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid...
متن کاملDibromido(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)(dimethyl sulfoxide-κO)cadmium
In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra-molecular C-H⋯O hydrogen bond occurs between the DMBP and DMSO ligands. π-π stacking between pyridine r...
متن کامل